2,713 research outputs found

    Dashed Hopes; Broken Promises; More Despair: How the Lack of State Participation in the Medicaid Expansion Will Punish Americans with Mental Illness

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    This comprehensive study shows that 6.7 million uninsured people with a mental illness are currently eligible for coverage under the Medicaid Expansion that went into effect on Jan. 1, 2014. But the majority of these individuals with mental health conditions will be left out in the coverage cold due to their state's antagonism toward the Medicaid Expansion health insurance initiative

    Involvement of titanocene and related species in the reduction of dinitrogen and olefins

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    Journal ArticleSummary Four sequential products have been spectrally detected in the reduction by sodium of dicyclopentadienyltitanium(iv) dichloride: [(77-Cp)2TiCl]2, [(77-Cp)2-Ti]1-2, [(77-Cp)(C5H4)TiH]x, and (77-Cp)(C5H4)TiH2Ti- (C5H4)(77-Cp) ("stable titanocene"); the second of these reacts rapidly and reversibly with N2 to give a dark blue complex reducible to ammonia and appears to catalyse the cyclopentadienyltitanium-promoted rapid, room temperature-atmospheric pressure hydrogenation of olefins

    Isolation and structural determination of {(1,1,2,2-tetracyano-1,2-ethanediyl)bis[imino(cyanomethylene)]}bis-(cyanamide) ion(2--), [C12N12]2--, a new cyanocarbon

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    Journal ArticleThe oxidative degradation of [N(PPh3)2]3[Mnilll(CN)6] leads to the isolation of the unprecedented [C12N12]2- dianion, which is characterized by single-crystal X-ray diffraction and spectroscopic techniques

    Structure and physical properties of hexacyanomanganate(IV), [MnIV(CN)6]2-

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    Journal ArticleHydrolytically unstable d3 [MnI V(CN)6]2- as the [N(PPh3)2]+ salt is crystallographically, spectroscopically, and magnetically characterized

    Far-infrared powder spectrum of (N(CH3)3D)(I)(TCNQ)

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    Journal ArticleWe present the powder absorption spectrum of (TMA)(I)(TCNQ) in the far-infrared as a function of temperature. Below 160 K new absorption features appear and others increase in intensity. This behaviour supports the electron- neutron-diffraction evidence of a distortion on the TCNQ chains below the first phase-transition temperature. Effects due to the second phase transition at 89 K are also observed. The results of a group-theoretical analysis are presented. These show that totally-symmetric internal modes ag are to be expected in the infrared spectra of this compound even in the undistorted phase

    Potential technology directions of molecular metals

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    Journal ArticleIn the past decade, anisotropic molecular conductors have been found which possess unusual electrical, optical, magnetic, and in some cases mechanical properties. Exploiting these properties for specific devices is inevitable, and a number of diverse applications of molecular metals have been reported over the past few years

    Far-infrared properties of trimethylammonium iodide tetracyanoquinodimethane

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    Journal ArticleWe present the powder absorption spectrum of (TMA) (I)(TCNQ) in the far-infrared as a function of temperature. Below 16 K new absorption features appear and others increase in intensity. This behaviour supports the electron and neutron diffraction evidence of a distortion on the TCNQ chains below the first phase transition temperature of 159 K (in the deuterated sample
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